This review of a new Afghan Whigs album is really lovely, and has me wanting to listen to it:
https://pitchfork.com/reviews/albums/the-afghan-whigs-how-do-you-burn/
I only know of them because one of you (I'm 90% sure it was LJT) included John the Baptist on a DI playlist, and I love that song. It's horny as lol, but pulls it off well. I also recall checking them out at Coachella in 2014 but it was a pretty sparse crowd and I didn't know any of the songs.
Pretty sure I had a Whigs track on one of mine, and then a Twilight Singers track on another. Huge, huge fan here.
I really would dissuade you from
pulling a Cobbler starting with a late-period album though; while the recent LPs have all been enjoyable to one extent or another, the absence of the band's original guitarist Rick McCollum results in a major downgrade between the classic 90s run and the albums post-"reunion" (only Dulli and bassist John Curley returned).
John The Baptist is from their last pre-breakup album 1965, and it has a great mixture of rock and r&b, recorded in New Orleans at Daniel Lanois's studio (and they cheekily named the instrumental closing track after him). The song Citi Soleil is one of the best Rolling Stones songs you've never heard, a bastard cousin of Gimme Shelter. It's probably their poppiest, most accessible.
There's also their breakthrough Gentlemen, which is an epic, self-flagellating tour through the wreckage of Dulli's romantic/sex life that is a masterpiece with a lot of great stuff, but might be too of its time for a new listener. The title track was a staple of college radio in 1993 and is pretty representative. There's also a great duet with vocalist Marcy Mays on My Curse.
For my money, the band's greatest masterpiece is 1996's Black Love, which is a film noir/crime fiction-inspired, loose concept album soaked in Los Angeles atmosphere, bringing in influences as disparate as Prince's Purple Rain (the song), Stevie Wonder's Superstition, The Who at their most anthemic, as well as their own brand of alternative rock with McCallum's signature slide guitar work. And the opening and closing tracks are two of the best album bookends I've ever heard.
Here's a ranked look at their catalog up through Do To The Beast, the first comeback album, that's well-observed, and the placements aren't too far off what I would do myself (I'd have 1965 higher, personally):
The Afghan Whigs Albums From Worst To Best
Happy hunting!